{(E)-2-Bromo-4-chloro-6-[3-(dimethylammonio)propyliminomethyl]phenolato}dichloridozinc(II)
نویسندگان
چکیده
The title compound, [ZnCl(2)(C(12)H(16)BrClN(2)O)], is a mononuclear zinc(II) complex. The Zn(II) atom is four-coordinate in a tetra-hedral geometry, binding to the phenolate O and imine N atoms of the zwitterionic Schiff base ligand and to two Cl(-) ions. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯Cl hydrogen bonds to form chains running along the a axis.
منابع مشابه
Redetermination of {2-[3-(dimethylammonio)propyliminomethyl]phenolato}dithiocyanatozinc(II)
In comparison with the previous refinement of the title complex, [Zn(NCS)(2)(C(12)H(18)N(2)O)], the present redetermination reveals a different location of the non-carbon attached H atom. Whereas in the previous refinement this H atom was modelled as part of a phenol OH group, the present study indicates a zwitterionic Schiff base ligand with a deprotonated OH group and a protonated tertiary am...
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In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra-coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The inter-planar dihedral angles between the benzene and pyridi...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008